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Directly irradiated fluidized bed reactors for thermochemical processing and energy storage: Application to calcium looping

机译:用于热化学处理和储能的直接辐照流化床反应器:应用于钙循环

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摘要

Directly irradiated fluidized bed reactors are very promising in the context of concentrated solar power\udapplications, as they can be operated at process temperatures high enough to perform thermochemical storage reactions\udwith high energy density. Limestone calcination-carbonation is an appealing reaction for thermochemical storage\udapplications due to the cheapness of the raw material, and the interesting value of the reaction enthalpy at fairly high\udprocess temperatures. Moreover, limestone calcination-carbonation is intensively studied in Calcium Looping (CaL)\udapplication for post combustion CO2 capture and sequestration. In this work, the dynamics of a directly irradiated 0.1\udm ID fluidized bed reactor exposed to a 12 kWel simulated solar furnace is analyzed with specific reference to\udtemperature distribution at the surface and in the bulk of the bed. Simulation of the solar radiation was performed through\udan array of three short arc Xe-lamps coupled with elliptical reflectors, yielding a peak flux of nearly 3000 kW m–2 and a\udtotal power of nearly 3 kW incident on the bed surface. Moreover, the directly irradiated fluidized bed reactor has been\udused to perform CaL tests by alternating solar-driven limestone calcination and autothermal recarbonation of lime. CaL\udhas been investigated with the twofold perspective of: a) accomplishing energy storage by solar-driven calcination of\udlimestone; b) perform solar-aided CO2 capture from flue gas to be embodied in carbon capture and sequestration\udschemes.
机译:直接辐照流化床反应器在聚光太阳能应用中非常有前途,因为它们可以在足够高的过程温度下进行,以进行具有高能量密度的热化学存储反应。石灰石煅烧碳酸化是热化学存储应用的一个吸引人的反应,这是因为原料便宜,并且在相当高的处理温度下反应焓的有趣值。此外,在钙循环(CaL)\ ud应用中对石灰石的煅烧碳酸化进行了深入研究,以用于燃烧后二氧化碳的捕获和封存。在这项工作中,对暴露于12 kWel模拟太阳能炉的直接辐照的0.1 \ udm ID流化床反应器的动力学进行了分析,并特别参考了床表面和整个床体的高温分布。太阳辐射的模拟是通过将三个短弧Xe灯与椭圆形反射镜耦合而形成的,其产生的峰值通量接近3000 kW m–2,总功率入射到床表面上约3 kW。此外,直接照射流化床反应器已被用于通过交替进行太阳驱动的石灰石煅烧和石灰的自热重碳化来进行CaL测试。已从以下两个方面研究了CaL \ ud:a)通过太阳驱动的\ udlimestone煅烧来完成能量存储; b)从烟气中进行太阳能辅助的CO2捕集,具体体现在碳捕集与封存\化学过程中。

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